Structural Biochemistry/Phase Equilibria

Introduction

More than one phases coexist at the same temperature and pressure.

K-values is a phase-equilibrium ratio, for vapor-liquid systems,

$K_{i} = y_{i} / x_{i}$

$y_{i}$ is the mole fraction of a species in vapor phase, and $x_{i}$ is the mole fraction of a species in liquid phase.

For ideal solutions,

$K_{i} = P_{i}^{S} / P$

K-values can be used for calculating bubble and dew points.

Seader, J. D., and Ernest J. Henley. Separation Process Principles. Hoboken, NJ: Wiley, 2006. Print.